"Size-segregated and Bulk Aerosol Data - Bellows Air Force Base, Hawaii, Sept. 1999" University of Virginia/Massachusetts Institute of Technology File Date - 28 August 2000 - NO3- data for cascade impactor #CI15 have been corrected " Sierra 325 cascade impactors configured with precleaned ""frosted"" Lexan (polycarbonate) impaction substrates and quartz fiber (Pallflex 2500 QAT-UP) backup filters." Bulk samplers configured with quartz fiber filters (Pallflex 2500 QAT-UP) " Average 50% aerodynamic cut diameters for impactor stages 0 thourgh 5 are 15, 8.4, 3.3, 1.8, 0.9, and 0.47 um, respectively. " " Corresponding ambient geometric mean diameters for each aerosol size fraction are 21, 11, 5.2, 2.4, 1.3, 0.65, and 0.33 um, respectively." All times in UTC SCM refers to standard cubic meter at 0 degree C and 1 atm. " Average measurement precision for Cl-, SO4-, NO3-, NH4+, Na+, K+, Mg2+, and Ca2+ is about +/-10%; average precision for CH3SO3-, COOHCOO-, and Br- is about +/-15%. " Detection limits (see bottom of sheet) were estimated as per Keene et al. (1989) based on estimated sample-volume uncertainties of +/-5%. " Negative values result from random analytical variability around low ambinent concentrations; they must be implemented as reported to generate reliable population statistics (e.g., average values)." " Sea-salt (ss) and non-sea-salt (nss) concentrations were calculated based on Na+ as a reference species and the seawater composition reported by Wilson (1975) (see Keene et al., 1986)" RESULTS Sample StartDate StartTime StopDate StopTime AirVolume Stage CH3SO3- Cl- SO4- COOHCOO- Br- NO3- NH4+ Na+ K+ Ca2+ Mg2+ ID ddmmyy hhmm ddmmyy hhmm SCM or Filter nmol/SCM nmol/SCM nmol/SCM nmol/SCM nmol/SCM nmol/SCM nmol/SCM nmol/SCM nmol/SCM nmol/SCM nmol/SCM CI1S0S 40999 450 40999 1618 810.9 0 0.002 22.023 1.173 -0.002 0.013 0.146 0.032 20.583 0.397 0.445 2.353 CI1S1S 40999 450 40999 1618 810.9 1 0.016 57.284 3.076 0.019 0.023 0.808 0.042 49.422 1.032 1.088 5.754 CI1S2S 40999 450 40999 1618 810.9 2 0.034 38.677 2.149 0.052 0.009 1.225 0.035 35.260 0.715 0.753 4.125 CI1S3S 40999 450 40999 1618 810.9 3 0.059 19.181 1.153 0.069 -0.001 1.038 0.030 19.553 0.375 0.395 2.127 CI1S4S 40999 450 40999 1618 810.9 4 0.086 9.420 0.695 0.072 0.000 0.607 0.030 8.733 0.192 0.204 1.030 CI1S5S 40999 450 40999 1618 810.9 5 0.049 0.968 0.613 0.039 -0.001 0.477 0.213 1.689 0.043 0.046 0.192 CI1S6S 40999 450 40999 1618 810.9 B 0.100 -0.100 4.195 0.075 0.023 0.003 2.445 3.456 0.744 0.288 0.114 Sum CI1S 40999 450 40999 1618 810.9 Sum 0.345 147.452 13.054 0.325 0.067 4.304 2.828 138.696 3.498 3.220 15.696 BU1S 40999 450 40999 1618 1011.1 Bulk 0.362 155.196 13.053 0.379 0.042 3.992 0.703 128.078 2.604 2.960 16.051 CI2S0S 40999 1635 50999 500 874.2 0 -0.001 20.580 1.073 -0.001 0.012 0.161 0.018 17.896 0.375 0.411 2.114 CI2S1S 40999 1635 50999 500 874.2 1 0.012 45.797 2.441 0.026 0.013 0.825 0.022 39.271 0.828 0.891 4.691 CI2S2S 40999 1635 50999 500 874.2 2 0.047 46.994 2.604 0.076 0.009 1.864 0.028 41.779 0.887 0.946 4.921 CI2S3S 40999 1635 50999 500 874.2 3 0.065 17.414 1.080 0.072 0.002 1.262 0.025 17.180 0.341 0.379 1.949 CI2S4S 40999 1635 50999 500 874.2 4 0.091 8.252 0.639 0.080 0.001 0.707 0.027 8.154 0.175 0.188 0.962 CI2S5S 40999 1635 50999 500 874.2 5 0.060 1.119 0.607 0.051 -0.001 0.061 0.167 1.884 0.049 0.052 0.217 CI2S6S 40999 1635 50999 500 874.2 B 0.129 -0.076 4.526 0.074 0.018 -0.002 2.328 4.201 0.807 0.343 0.122 Sum CI2S 40999 1635 50999 500 874.2 Sum 0.402 140.079 12.973 0.378 0.055 4.879 2.615 130.365 3.462 3.210 14.975 BU2S 40999 1635 50999 500 1095.9 Bulk 0.433 135.095 12.711 0.437 0.046 5.006 0.964 126.745 2.906 3.241 14.498 CI3S0S 70999 455 70999 1607 792.0 0 0.000 9.775 0.511 0.000 0.017 0.032 0.016 8.083 0.170 0.205 0.972 CI3S1S 70999 455 70999 1607 792.0 1 0.004 23.686 1.287 0.008 0.023 0.280 0.018 21.205 0.430 0.456 2.448 CI3S2S 70999 455 70999 1607 792.0 2 0.012 17.406 1.025 0.029 0.011 0.658 0.019 16.591 0.326 0.349 1.967 CI3S3S 70999 455 70999 1607 792.0 3 0.014 4.969 0.377 0.032 -0.001 0.428 0.024 4.582 0.106 0.117 0.555 CI3S4S 70999 455 70999 1607 792.0 4 0.018 1.918 0.268 0.032 -0.001 0.235 0.045 4.216 0.095 0.034 0.261 CI3S5S 70999 455 70999 1607 792.0 5 0.023 0.099 0.413 0.016 -0.001 0.377 0.191 0.346 0.013 0.013 0.044 CI3S6S 70999 455 70999 1607 792.0 B 0.105 0.058 2.209 0.028 -0.001 0.000 0.161 3.138 0.173 0.065 0.027 Sum CI3S 70999 455 70999 1607 792.0 Sum 0.176 57.912 6.090 0.145 0.046 2.010 0.474 58.160 1.314 1.239 6.273 BU3S 70999 455 70999 1607 988.5 Bulk 0.201 55.624 6.434 0.192 0.036 1.656 0.229 53.279 1.317 1.523 5.836 CI4S0S 70999 1619 80999 416 801.9 0 0.000 9.051 0.498 -0.002 0.005 0.071 0.006 7.411 0.161 0.185 0.901 CI4S1S 70999 1619 80999 416 801.9 1 0.007 10.386 0.603 0.009 0.008 0.256 0.006 8.748 0.193 0.213 1.064 CI4S2S 70999 1619 80999 416 801.9 2 0.032 17.529 1.125 0.034 0.007 0.838 0.016 15.055 0.337 0.356 1.817 CI4S3S 70999 1619 80999 416 801.9 3 0.052 8.424 0.675 0.044 -0.001 0.748 0.024 7.851 0.176 0.195 0.968 CI4S4S 70999 1619 80999 416 801.9 4 0.074 3.923 0.481 0.059 -0.001 0.469 0.034 4.239 0.091 0.109 0.505 CI4S5S 70999 1619 80999 416 801.9 5 0.058 0.105 0.904 0.030 0.001 1.071 0.251 0.750 0.024 0.024 0.089 CI4S6S 70999 1619 80999 416 801.9 B 0.116 0.218 3.111 0.063 -0.001 0.007 0.378 3.797 0.371 0.262 0.091 Sum CI4S 70999 1619 80999 416 801.9 Sum 0.339 49.636 7.398 0.237 0.018 3.459 0.716 47.851 1.353 1.345 5.434 BU4S 70999 1619 80999 416 1054.7 Bulk 0.342 50.011 7.465 0.280 -0.001 2.477 0.489 51.321 1.364 1.461 5.447 CI5S0S 110999 430 110999 1610 819.0 0 0.001 13.992 0.794 0.010 0.015 0.190 0.004 11.755 0.253 0.270 1.366 CI5S1S 110999 430 110999 1610 819.0 1 0.004 17.964 1.045 0.020 0.017 0.458 0.011 14.920 0.336 0.349 1.761 CI5S2S 110999 430 110999 1610 819.0 2 0.012 24.383 1.495 0.071 0.014 1.080 0.024 23.183 0.466 0.475 2.682 CI5S3S 110999 430 110999 1610 819.0 3 0.019 12.550 0.861 0.097 0.002 0.888 0.038 11.463 0.257 0.274 1.349 CI5S4S 110999 430 110999 1610 819.0 4 0.024 5.698 0.557 0.101 0.000 0.490 0.051 5.680 0.130 0.138 0.694 CI5S5S 110999 430 110999 1610 819.0 5 0.030 0.552 0.568 0.059 0.001 1.013 0.230 1.377 0.046 0.034 0.128 CI5S6S 110999 430 110999 1610 819.0 B 0.108 -0.134 3.075 0.096 0.020 -0.001 1.254 3.593 0.541 0.187 0.072 Sum CI5S 110999 430 110999 1610 819.0 Sum 0.199 75.005 8.394 0.454 0.069 4.119 1.612 71.972 2.027 1.728 8.052 BU5S 110999 430 110999 1610 1024.0 Bulk 0.223 89.448 9.523 0.580 0.066 3.462 0.483 85.477 2.081 2.263 9.624 CI6S0S 110999 1630 120999 410 786.1 0 0.002 9.515 0.526 0.002 0.008 0.092 0.008 7.878 0.174 0.208 0.962 CI6S1S 110999 1630 120999 410 786.1 1 0.014 39.228 2.195 0.019 0.024 0.496 0.031 35.042 0.714 0.757 4.051 CI6S2S 110999 1630 120999 410 786.1 2 0.030 29.392 1.717 0.042 0.014 0.898 0.031 27.738 0.557 0.592 3.109 CI6S3S 110999 1630 120999 410 786.1 3 0.040 13.366 0.878 0.046 -0.001 0.764 0.036 11.872 0.262 0.295 1.365 CI6S4S 110999 1630 120999 410 786.1 4 0.063 6.539 0.592 0.055 0.000 0.520 0.048 6.287 0.148 0.160 0.759 CI6S5S 110999 1630 120999 410 786.1 5 0.054 0.210 0.848 0.031 -0.001 0.807 0.294 1.150 0.040 0.043 0.050 CI6S6S 110999 1630 120999 410 786.1 B 0.092 0.197 2.334 0.041 0.013 0.012 0.288 3.337 0.232 0.154 0.058 Sum CI6S 110999 1630 120999 410 786.1 Sum 0.297 98.447 9.090 0.236 0.057 3.588 0.737 93.304 2.125 2.209 10.354 BU6S 110999 1630 120999 410 1017.1 Bulk 0.370 120.312 11.110 0.332 0.031 3.404 0.795 108.848 2.605 2.940 12.613 CI7S0S 120999 430 120999 1606 399.3 0 0.000 6.894 0.382 -0.005 -0.002 0.081 0.029 5.959 0.124 0.139 0.700 CI7S1S 120999 430 120999 1606 399.3 1 0.015 33.542 1.881 0.006 0.016 0.607 0.039 28.095 0.613 0.645 3.298 CI7S2S 120999 430 120999 1606 399.3 2 0.038 29.623 1.786 0.041 -0.002 1.218 0.042 25.188 0.552 0.603 2.982 CI7S3S 120999 430 120999 1606 399.3 3 0.051 10.123 0.748 0.040 0.004 0.735 0.068 9.526 0.203 0.231 1.120 CI7S4S 120999 430 120999 1606 399.3 4 0.053 4.410 0.494 0.049 0.007 0.419 0.085 4.681 0.106 0.087 0.552 CI7S5S 120999 430 120999 1606 399.3 5 0.037 0.360 0.545 0.021 -0.001 0.204 0.522 0.803 0.029 0.037 0.099 CI7S6S 120999 430 120999 1606 399.3 B 0.077 -0.460 2.797 0.056 0.000 0.012 0.333 2.119 0.211 0.103 0.039 Sum CI7S 120999 430 120999 1606 399.3 Sum 0.271 84.491 8.633 0.209 0.021 3.276 1.117 76.370 1.839 1.843 8.790 BU7S 120999 430 120999 1606 1004.1 Bulk 0.298 89.827 9.427 0.279 0.045 3.740 0.331 87.179 1.964 2.167 9.716 CI8S0S 120999 1630 130999 400 803.5 0 0.001 10.143 0.544 -0.001 0.010 0.067 0.016 8.401 0.183 0.205 0.999 CI8S1S 120999 1630 130999 400 803.5 1 0.009 27.771 1.537 0.019 0.025 0.440 0.019 24.798 0.502 0.518 2.781 CI8S2S 120999 1630 130999 400 803.5 2 0.019 22.230 1.292 0.030 0.014 0.791 0.021 21.420 0.412 0.418 2.294 CI8S3S 120999 1630 130999 400 803.5 3 0.024 9.078 0.608 0.031 0.002 0.639 0.027 8.309 0.179 0.185 0.977 CI8S4S 120999 1630 130999 400 803.5 4 0.028 3.715 0.374 0.033 0.000 0.386 0.041 3.785 0.079 0.080 0.437 CI8S5S 120999 1630 130999 400 803.5 5 0.022 0.423 0.343 0.017 -0.001 0.161 0.168 0.787 0.023 0.028 0.093 CI8S6S 120999 1630 130999 400 803.5 B 0.080 -0.451 2.459 0.055 0.010 0.003 0.334 2.124 0.206 0.084 0.034 Sum CI8S 120999 1630 130999 400 803.5 Sum 0.183 72.910 7.157 0.185 0.059 2.487 0.626 69.623 1.583 1.518 7.616 BU8S 120999 1630 130999 400 1005.1 Bulk 0.187 74.369 7.153 0.210 0.036 2.387 0.365 69.434 1.706 1.902 7.494 CI9S0S 160999 430 160999 1609 821.5 0 0.002 17.449 0.951 0.006 0.000 -0.001 0.009 14.582 0.326 0.318 1.675 CI9S1S 160999 430 160999 1609 821.5 1 0.004 19.064 1.058 0.008 0.006 0.325 0.011 17.521 0.341 0.350 1.964 CI9S2S 160999 430 160999 1609 821.5 2 0.029 39.296 2.263 0.055 0.009 1.268 0.017 37.600 0.724 0.737 4.092 CI9S3S 160999 430 160999 1609 821.5 3 0.034 17.443 1.113 0.060 0.003 0.972 0.015 15.550 0.346 0.345 1.762 CI9S4S 160999 430 160999 1609 821.5 4 0.054 8.417 0.735 0.073 -0.001 0.616 0.017 7.977 0.176 0.176 0.964 CI9S5S 160999 430 160999 1609 821.5 5 0.036 0.770 0.678 0.044 -0.001 0.022 0.186 1.629 0.039 0.049 0.191 CI9S6S 160999 430 160999 1609 821.5 B 0.068 -0.443 2.952 0.059 0.002 0.003 0.577 2.776 0.331 0.174 0.060 Sum CI9S 160999 430 160999 1609 821.5 Sum 0.228 101.996 9.750 0.305 0.017 3.205 0.831 97.636 2.283 2.149 10.708 BU9S 160999 430 160999 1609 1013.1 Bulk 0.267 124.447 11.704 0.407 0.059 3.983 0.880 114.636 2.746 2.892 13.324 CI10S0S 160999 1636 170999 415 692.6 0 0.000 16.721 0.902 0.005 0.019 0.038 0.003 13.967 0.300 0.581 1.596 CI10S1S 160999 1636 170999 415 692.6 1 0.006 33.159 1.835 0.015 0.033 0.193 0.005 28.469 0.606 1.126 3.257 CI10S2S 160999 1636 170999 415 692.6 2 0.026 50.691 2.862 -0.002 0.030 0.893 0.009 43.844 0.926 1.568 5.094 CI10S3S 160999 1636 170999 415 692.6 3 0.030 19.371 1.215 0.041 0.004 0.763 0.009 17.031 0.376 0.653 1.957 CI10S4S 160999 1636 170999 415 692.6 4 0.048 9.595 0.794 0.054 -0.001 0.665 0.018 9.153 0.198 0.400 1.080 CI10S5S 160999 1636 170999 415 692.6 5 0.043 0.650 0.907 0.028 -0.002 0.031 0.274 1.720 0.047 0.104 0.202 CI10S6S 160999 1636 170999 415 692.6 B 0.077 0.298 2.706 0.045 0.018 0.042 0.334 3.229 0.251 0.313 0.102 Sum CI10S 160999 1636 170999 415 692.6 Sum 0.231 130.485 11.223 0.187 0.101 2.625 0.652 117.413 2.705 4.745 13.290 BU10S 160999 1636 170999 415 892.9 Bulk 0.277 174.524 13.701 0.388 0.087 3.891 1.013 152.514 3.505 5.411 17.494 CI11S0S 170999 425 170999 1615 806.2 0 0.000 16.485 0.870 -0.002 0.011 0.117 0.036 13.954 0.304 0.305 1.613 CI11S1S 170999 425 170999 1615 806.2 1 0.006 22.021 1.214 0.006 0.008 0.389 0.034 20.702 0.403 0.406 2.202 CI11S2S 170999 425 170999 1615 806.2 2 0.025 31.951 1.849 0.042 0.010 1.062 0.037 29.508 0.594 0.609 3.260 CI11S3S 170999 425 170999 1615 806.2 3 0.042 15.771 1.018 0.052 0.006 0.830 0.037 14.156 0.316 0.333 1.648 CI11S4S 170999 425 170999 1615 806.2 4 0.064 8.141 0.737 0.067 0.000 0.506 0.042 7.730 0.171 0.174 0.927 CI11S5S 170999 425 170999 1615 806.2 5 0.044 0.506 0.826 0.032 0.000 0.076 0.291 1.445 0.036 0.044 0.167 CI11S6S 170999 425 170999 1615 806.2 B 0.088 -0.191 3.279 0.055 0.014 0.004 0.911 3.051 0.398 0.196 0.081 Sum CI11S 170999 425 170999 1615 806.2 Sum 0.268 94.684 9.794 0.253 0.050 2.984 1.388 90.547 2.222 2.067 9.897 BU11S 170999 425 170999 1615 1000.7 Bulk 0.310 117.364 11.680 0.351 0.070 3.306 0.332 106.876 2.458 2.814 12.443 CI12S0S 170999 1633 180999 410 789.0 0 0.002 16.168 0.905 -0.002 0.010 0.143 0.031 13.536 0.291 0.404 1.569 CI12S1S 170999 1633 180999 410 789.0 1 0.009 21.570 1.218 0.014 0.013 0.405 0.033 19.035 0.395 0.413 2.101 CI12S2S 170999 1633 180999 410 789.0 2 0.030 36.197 2.114 0.054 0.007 1.264 0.041 33.589 0.674 0.692 3.657 CI12S3S 170999 1633 180999 410 789.0 3 0.033 15.738 1.037 0.053 0.000 0.927 0.038 14.314 0.308 0.328 1.637 CI12S4S 170999 1633 180999 410 789.0 4 0.050 7.718 0.701 0.068 0.001 0.560 0.046 7.395 0.167 0.168 0.878 CI12S5S 170999 1633 180999 410 789.0 5 0.050 0.211 1.137 0.044 0.002 0.051 0.596 1.325 0.040 0.042 0.155 CI12S6S 170999 1633 180999 410 789.0 B 0.089 -0.484 3.059 0.058 0.010 -0.007 0.637 2.671 0.379 0.184 0.075 Sum CI12S 170999 1633 180999 410 789.0 Sum 0.263 97.118 10.171 0.289 0.043 3.343 1.424 91.864 2.255 2.230 10.072 BU12S 170999 1633 180999 410 1015.3 Bulk 0.318 134.839 12.722 0.373 0.043 4.121 0.495 122.411 2.840 3.177 14.334 CI13S0S 200999 1630 210999 410 821.3 0 0.001 7.195 0.401 0.001 0.010 0.054 0.024 6.011 0.132 0.141 0.713 CI13S1S 200999 1630 210999 410 821.3 1 0.009 29.910 1.703 0.012 0.023 0.282 0.027 26.549 0.556 0.561 2.975 CI13S2S 200999 1630 210999 410 821.3 2 0.015 24.884 1.519 0.033 0.010 0.553 0.032 24.134 0.463 0.480 2.460 CI13S3S 200999 1630 210999 410 821.3 3 0.020 8.685 0.647 0.030 0.001 0.362 0.041 7.907 0.167 0.170 0.917 CI13S4S 200999 1630 210999 410 821.3 4 0.029 4.041 0.492 0.037 0.002 0.233 0.054 4.065 0.089 0.087 0.481 CI13S5S 200999 1630 210999 410 821.3 5 0.024 0.314 0.456 0.028 -0.001 0.028 0.270 0.744 0.019 0.032 0.087 CI13S6S 200999 1630 210999 410 821.3 B 0.043 0.382 1.476 0.032 -0.001 0.005 0.010 2.693 0.091 0.027 0.005 Sum CI13S 200999 1630 210999 410 821.3 Sum 0.140 75.410 6.694 0.173 0.043 1.517 0.457 72.103 1.517 1.497 7.637 BU13S 200999 1630 210999 410 1018.4 Bulk 0.161 85.746 7.563 0.204 0.046 1.434 0.264 78.983 1.851 2.059 8.394 CI14S0S 210999 433 210999 1610 796.6 0 0.000 7.409 0.411 -0.001 0.008 0.048 0.033 6.245 0.133 0.149 0.732 CI14S1S 210999 433 210999 1610 796.6 1 0.004 14.920 0.825 0.002 0.012 0.127 0.031 12.491 0.273 0.294 1.420 CI14S2S 210999 433 210999 1610 796.6 2 0.012 24.281 1.411 0.025 0.017 0.435 0.031 23.049 0.448 0.477 2.425 CI14S3S 210999 433 210999 1610 796.6 3 0.017 8.669 0.584 0.022 0.000 0.332 0.036 7.744 0.166 0.166 0.901 CI14S4S 210999 433 210999 1610 796.6 4 0.020 3.624 0.369 0.023 0.001 0.202 0.043 3.585 0.075 0.069 0.407 CI14S5S 210999 433 210999 1610 796.6 5 0.019 0.309 0.345 0.020 -0.001 0.076 0.203 0.596 0.012 0.020 0.071 CI14S6S 210999 433 210999 1610 796.6 B 0.041 -0.063 1.235 0.024 0.001 0.004 0.003 1.348 0.036 0.017 0.005 Sum CI14S 210999 433 210999 1610 796.6 Sum 0.113 59.150 5.179 0.116 0.037 1.224 0.380 55.059 1.143 1.192 5.961 BU14S 210999 433 210999 1610 1025.3 Bulk 0.130 91.426 7.032 0.166 0.051 1.476 0.314 78.249 1.920 2.153 9.081 CI15S0S 210999 1632 220999 415 819.1 0 0.000 13.374 0.720 0.010 0.008 -0.002 0.025 11.341 0.246 0.249 1.340 CI15S1S 210999 1632 220999 415 819.1 1 0.011 57.774 3.087 0.027 0.033 0.403 0.029 50.072 1.038 1.064 5.607 CI15S2S 210999 1632 220999 415 819.1 2 0.018 36.855 2.019 0.036 0.005 0.641 0.030 32.356 0.668 0.685 3.701 CI15S3S 210999 1632 220999 415 819.1 3 0.028 17.908 1.061 0.045 -0.002 0.611 0.030 17.445 0.336 0.366 1.858 CI15S4S 210999 1632 220999 415 819.1 4 0.041 8.599 0.651 0.054 -0.001 0.393 0.032 8.184 0.175 0.177 0.952 CI15S5S 210999 1632 220999 415 819.1 5 0.029 16.986 1.012 0.044 -0.003 0.589 0.024 11.266 0.331 0.339 1.727 CI15S6S 210999 1632 220999 415 819.1 B 0.056 -0.021 2.119 0.048 0.012 -0.014 0.036 2.254 0.091 0.068 0.332 Sum CI15S 210999 1632 220999 415 819.1 Sum 0.184 151.474 10.669 0.264 0.053 2.621 0.205 132.918 2.885 2.948 15.518 BU15S 210999 1632 220999 415 1021.7 Bulk 0.206 154.763 11.055 0.275 0.043 2.437 0.315 133.691 2.953 3.281 15.655 CI16S0S 220999 439 220999 1615 792.5 0 0.002 10.251 0.551 0.002 0.009 0.071 0.018 8.737 0.186 0.202 1.018 CI16S1S 220999 439 220999 1615 792.5 1 0.009 42.329 2.278 0.018 0.032 0.422 0.019 36.605 0.767 0.775 4.217 CI16S2S 220999 439 220999 1615 792.5 2 0.021 35.390 1.954 0.033 0.020 0.733 0.018 32.653 0.652 0.665 3.581 CI16S3S 220999 439 220999 1615 792.5 3 0.033 18.935 1.129 0.043 0.012 0.728 0.018 17.767 0.349 0.379 1.943 CI16S4S 220999 439 220999 1615 792.5 4 0.041 9.243 0.686 0.050 0.004 0.454 0.016 8.456 0.188 0.195 0.999 CI16S5S 220999 439 220999 1615 792.5 5 0.035 0.611 0.728 0.027 -0.001 0.113 0.176 1.437 0.038 0.036 0.171 CI16S6S 220999 439 220999 1615 792.5 B 0.046 -0.376 1.906 0.035 0.004 -0.007 0.010 1.689 0.035 0.041 0.020 Sum CI16S 220999 439 220999 1615 792.5 Sum 0.187 116.383 9.231 0.208 0.081 2.515 0.274 107.346 2.215 2.292 11.949 BU16S 220999 439 220999 1615 1012.5 Bulk 0.223 163.498 12.199 0.288 0.092 2.833 0.237 143.566 3.143 3.456 16.461 CI17S0S 260999 430 260999 1610 790.2 0 0.001 25.564 1.370 0.004 0.019 0.140 0.016 23.764 0.462 0.471 2.505 CI17S1S 260999 430 260999 1610 790.2 1 0.001 29.674 1.618 0.021 0.015 0.370 0.019 26.934 0.544 0.566 2.985 CI17S2S 260999 430 260999 1610 790.2 2 0.014 55.427 3.072 0.077 0.014 1.234 0.031 48.337 1.025 1.072 5.479 CI17S3S 260999 430 260999 1610 790.2 3 0.016 23.429 1.415 0.080 0.006 0.848 0.025 20.857 0.451 0.497 2.372 CI17S4S 260999 430 260999 1610 790.2 4 0.023 12.386 0.928 0.106 -0.001 0.534 0.033 11.379 0.260 0.273 1.379 CI17S5S 260999 430 260999 1610 790.2 5 0.037 0.737 0.907 0.079 0.004 0.103 0.210 2.074 0.088 0.051 0.244 CI17S6S 260999 430 260999 1610 790.2 B 0.082 -0.161 2.496 0.101 0.025 -0.007 0.343 3.148 0.215 0.155 0.057 Sum CI17S 260999 430 260999 1610 790.2 Sum 0.175 147.057 11.806 0.467 0.082 3.221 0.677 136.493 3.046 3.085 15.022 BU17S 260999 430 260999 1610 1020.8 Bulk 0.179 184.188 13.577 0.549 0.112 3.341 0.785 162.034 3.696 4.095 18.835 CI18S0S 260999 1630 270999 410 822.6 0 -0.001 13.894 0.741 0.007 0.001 0.152 0.020 11.893 0.252 0.268 1.328 CI18S1S 260999 1630 270999 410 822.6 1 0.010 75.027 4.051 0.062 0.000 1.319 0.041 64.577 1.385 1.462 7.537 CI18S2S 260999 1630 270999 410 822.6 2 0.012 58.497 3.270 0.138 0.005 1.944 0.040 52.521 1.100 1.189 6.004 CI18S3S 260999 1630 270999 410 822.6 3 0.015 23.805 1.472 0.116 0.005 1.196 0.028 22.699 0.467 0.531 2.598 CI18S4S 260999 1630 270999 410 822.6 4 0.023 12.560 1.004 0.145 0.004 0.730 0.035 11.952 0.275 0.300 1.402 CI18S5S 260999 1630 270999 410 822.6 5 0.027 1.083 0.808 0.088 0.003 0.057 0.205 2.206 0.081 0.073 0.268 CI18S6S 260999 1630 270999 410 822.6 B 0.115 0.200 3.278 0.115 -0.002 0.001 1.058 4.947 0.468 0.175 0.072 SumCI18S 260999 1630 270999 410 822.6 Sum 0.202 185.065 14.625 0.671 0.016 5.400 1.427 170.795 4.028 3.999 19.209 BU18S 260999 1630 270999 410 1022.2 Bulk 0.269 229.938 18.119 0.916 0.090 6.173 0.825 204.720 4.401 5.111 23.673 CI19S0S 270999 436 270999 1610 794.6 0 0.000 9.303 0.493 0.002 0.001 0.152 0.019 7.954 0.168 0.176 0.937 CI19S1S 270999 436 270999 1610 794.6 1 0.002 22.936 1.267 0.020 0.006 0.573 0.019 20.348 0.429 0.462 2.346 CI19S2S 270999 436 270999 1610 794.6 2 0.014 39.562 2.257 0.084 0.002 1.874 0.023 35.719 0.762 0.854 4.042 CI19S3S 270999 436 270999 1610 794.6 3 0.018 18.156 1.171 0.109 0.001 1.285 0.018 16.681 0.400 0.427 1.938 CI19S4S 270999 436 270999 1610 794.6 4 0.024 8.424 0.749 0.114 0.001 0.752 0.024 8.388 0.206 0.207 1.006 CI19S5S 270999 436 270999 1610 794.6 5 0.043 0.136 1.109 0.079 0.004 0.047 0.542 1.376 0.068 0.052 0.170 CI19S6S 270999 436 270999 1610 794.6 B 0.124 -0.296 3.720 0.117 0.009 0.004 1.413 3.564 0.534 0.344 0.112 Sum CI19S 270999 436 270999 1610 794.6 Sum 0.225 98.220 10.766 0.525 0.023 4.688 2.058 94.029 2.567 2.522 10.551 BU19S 270999 436 270999 1610 1019.6 Bulk 0.261 150.452 14.166 0.690 0.041 6.317 0.898 142.777 3.194 3.677 16.434 CI20S0S 270999 1631 280999 410 820.3 0 0.000 5.938 0.331 0.001 0.002 0.189 0.009 5.100 0.120 0.141 0.614 CI20S1S 270999 1631 280999 410 820.3 1 0.006 14.512 0.883 0.031 0.003 1.444 0.025 13.400 0.180 0.373 1.543 CI20S2S 270999 1631 280999 410 820.3 2 0.018 25.136 1.718 0.130 0.000 4.216 0.051 27.347 0.566 0.720 3.050 CI20S3S 270999 1631 280999 410 820.3 3 0.015 8.157 0.690 0.127 -0.001 2.016 0.041 8.882 0.236 0.274 1.130 CI20S4S 270999 1631 280999 410 820.3 4 0.025 3.501 0.573 0.154 0.011 1.055 0.069 4.733 0.144 0.150 0.596 CI20S5S 270999 1631 280999 410 820.3 5 0.043 0.025 1.149 0.084 -0.001 0.033 0.984 0.859 0.072 0.039 0.108 CI20S6S 270999 1631 280999 410 820.3 B 0.161 -0.406 4.789 0.212 0.042 0.006 3.348 4.720 0.932 0.367 0.115 Sum CI20S 270999 1631 280999 410 820.3 Sum 0.268 56.863 10.132 0.739 0.057 8.959 4.527 65.042 2.249 2.064 7.156 BU20S 270999 1631 280999 410 1019.4 Bulk 0.323 61.300 11.578 0.869 0.050 9.861 4.181 70.913 2.552 2.306 8.080 CI21S0S 280999 533 280999 1610 722.5 0 0.000 13.987 0.782 0.011 0.020 0.156 0.021 11.815 0.274 0.422 1.420 CI21S1S 280999 533 280999 1610 722.5 1 0.012 26.789 1.716 0.050 0.022 0.985 0.030 26.567 0.570 0.850 2.816 CI21S2S 280999 533 280999 1610 722.5 2 0.019 14.246 1.118 0.082 0.000 1.425 0.051 13.628 0.375 0.474 1.571 CI21S3S 280999 533 280999 1610 722.5 3 0.017 5.199 0.562 0.092 0.002 0.954 0.064 5.762 0.166 0.197 0.701 CI21S4S 280999 533 280999 1610 722.5 4 0.021 2.134 0.486 0.107 -0.001 0.535 0.095 3.017 0.090 0.100 0.384 CI21S5S 280999 533 280999 1610 722.5 5 0.048 0.022 1.309 0.077 0.000 0.031 1.734 0.543 0.076 0.036 0.075 CI21S6S 280999 533 280999 1610 722.5 B 0.118 -0.002 3.277 0.163 0.020 0.062 0.714 4.827 0.407 0.221 0.076 Sum CI21S 280999 533 280999 1610 722.5 Sum 0.234 62.376 9.251 0.581 0.062 4.148 2.709 66.159 1.958 2.301 7.043 BU21S 280999 533 280999 1610 930.2 Bulk 0.263 68.030 10.111 0.723 0.054 5.082 0.438 71.883 2.008 2.626 7.942 CI22S0S 280999 1630 290999 410 822.6 0 0.001 4.287 0.240 0.003 0.004 0.065 0.022 3.737 0.078 0.073 0.427 CI22S1S 280999 1630 290999 410 822.6 1 0.005 16.361 0.929 0.018 0.004 0.363 0.020 14.283 0.313 0.318 1.640 CI22S2S 280999 1630 290999 410 822.6 2 0.024 24.140 1.466 0.051 0.005 1.044 0.027 22.953 0.469 0.503 2.612 CI22S3S 280999 1630 290999 410 822.6 3 0.048 13.866 0.971 0.071 0.003 1.009 0.030 13.037 0.284 0.293 1.474 CI22S4S 280999 1630 290999 410 822.6 4 0.087 8.315 0.826 0.095 0.001 0.771 0.038 8.487 0.190 0.185 1.003 CI22S5S 280999 1630 290999 410 822.6 5 0.051 0.806 0.672 0.055 -0.001 0.059 0.151 1.759 0.045 0.062 0.208 CI22S6S 280999 1630 290999 410 822.6 B 0.071 0.151 2.893 0.103 0.019 0.004 0.514 3.780 0.299 0.224 0.086 Sum CI22S 280999 1630 290999 410 822.6 Sum 0.286 67.926 7.997 0.396 0.034 3.314 0.803 68.036 1.679 1.660 7.451 BU22S 280999 1630 290999 410 1022.2 Bulk 0.304 83.433 9.070 0.471 0.024 3.622 0.406 78.895 1.860 2.103 9.084 FIELD BLANKS AND ESTIMATED DETECTION LIMITS Impaction Substrates (based on average sample volume of 781.7 SCM) Average of Blanks 0.0013 0.0351 0.0033 0.0016 0.0011 -0.0014 -0.0009 0.0172 0.000 -0.001 0.006 Standard Deviation of Blanks 0.0003 0.0121 0.0012 0.0014 0.0015 0.0022 0.0027 0.0107 0.002 0.005 0.002 Number of Blanks 36 33 35 36 35 35 36 33 36 36 35 Estimated Detection Limit 0.0010 0.0473 0.0048 0.0055 0.0059 0.0087 0.0106 0.0418 0.0083 0.0186 0.0079 Impactor Backup Filters (based on an average sample volume of 781.7 SCM) Average of Blanks 0.0011 0.8902 0.2651 0.0187 0.0009 0.0226 0.0374 4.7427 0.128 0.035 0.010 Standard Deviation of Blanks 0.0002 0.3003 0.0310 0.0128 0.0022 0.0066 0.0000 0.6230 0.019 0.007 0.002 Number of Blanks 12 11 11 11 12 11 12 12 11 10 11 Estimated Detection Limit 0.0008 1.1787 0.1217 0.0502 0.0087 0.0257 0.0000 2.4453 0.0758 0.0270 0.0066 Bulk Filters (based on an average sample volume of 1016.3 SCM) Average of Blanks 0.0009 0.6847 0.2039 0.0144 0.0007 0.0174 0.0288 3.6482 0.098 0.027 0.008 Standard Deviation of Blanks 0.0001 0.2310 0.0239 0.0098 0.0017 0.0050 0.0000 0.4792 0.015 0.005 0.001 Number of Blanks 12 11 11 11 12 11 12 12 11 10 11 Estimated Detection Limit 0.0006 0.9067 0.0936 0.0386 0.0067 0.0198 0.0000 1.8809 0.0583 0.0208 0.0051 FIELD NOTES Sample Set No. Remark 1 2 Forgot to remove Al cover from bulk filter cartridge; flow rate ~0. Pumps off 1632. Cover removed. Pumps on 1635. Flow rate normal. 3 Forgot to take cover off bulk filter blank. 4 5 "Impactor head ""B"" used for CI5S; unnamed head used for CI5B. Very light shower during blank exposure." 6 Wind lt. Offshore at start of interval. Impactor head E used. Faint gray shade visible on impactor stage 5 and bulk filter. 7 "Hivols off at 10:11; impactor ""whistling"". Bulk only restarted at 10:22. Found loose corner bolt on impactor at sample recovery time." 8 "Impactor B used. Part of bulk filter potentially contaminated during recovery by two drops of water that had adhered to hood from shower that occurred just prior to recovery. That section of filter is in tube marked with a *, I.e. ""BU8S*""." 9 Impactor B used for blank; unnamed head used for sample. 10 "Impactor E used. Pumps off for rain at 1752, back on at 1918." 11 Unnamed head used. Light shower at ~1430 (~5 min). Pumps off for rain at 1445; back on at 1508. 12 Impactor head E used. 13 "Shower during instalation of blanks; contamination unlikely. Impactor B used for blank; unnamed head used for sample. Forgot bulksample cap again; hivol pumps off 1631, back on 1637." 14 Impactor head E used. 15 Unlabeled impactor head E used. 16 "Impactor head E used. Light shower ~1130, pumps not shut off. 8x10 filters: 2500QAT-UP Lot No. 52606. 47mm quartz filters 2500QAT-UP Lot No. 51574." 17 Impactor B used for blank; head E used for sample. Slight gray tint on sample Stage 5.pollution aerosol? Sky hazy. 18 Unlabeled head used. Stage 5 gray again. Hazy all day.Molokai barely visible. Pink sunset. 19 Head E used. Stage 5 gray again. 20 Unlabeled head used. Molokai & Maui clearly visible at sunrise (start of interval). Stage 5 gray again.maybe more so than previous sample. 21 "Head E used. Delayed start due to along-shore wind (from N) then light shower. Stage 5 distinctly gray. Stages 4 & 6 also slightly gray. Light winds, some possibly offshore, during this interval." 22 "Unlabeled head used. Extremely clear at start of sample.Molokai & Maui (and possibly the Big Island) look like they're ""here"". Stage 5 barely perceptibly gray."